Color study of historic silks

  • María Luisa Vázquez de Ágredos Pascual ARSMAYA research group, Department of Art History, Universitat de València, Spain https://orcid.org/0000-0002-4433-8850
  • Rosa Herráez-Hernandez MINTOTA research group, Departament de Química Analítica, Facultat de Química, Universitat de València, Spain https://orcid.org/0000-0002-5106-0826
  • Pilar Campíns-Falcó MINTOTA research group, Departament de Química Analítica, Facultat de Química, Universitat de València, Spain https://orcid.org/0000-0002-0980-8298
  • Lucía Rojo Iranzo Technician of the Laboratory of Analysis and Diagnosis of Work of Art, Department of Art History, Universitat de València, Spain
  • Ester Alba Pagán VALuART research group, Department of Art History, Universitat de València, Spain https://orcid.org/0000-0003-0858-1156
Keywords: silks, colour, diffuse reflectance spectroscopy, natural dyes, Fourier transformed infrared - attenuated total reflectance (FTIR-ATR), microscopic image by LM, LMi and SEM image, SILKNOW

Abstract

The chemical characterization of silk textiles of historic value may be necessary to achieve a better understanding of the production processes applied, to evaluate their preservation, to detect manipulations or forgeries, and to value the combination of tradition and innovation in contemporary manufacturing techniques. The main objective of this work was to study four historical silks from the Garín collection, all of them from the 20th century, although with 19th century designs. To this end, non-invasive spectroscopic and microscopy techniques were applied in order to obtain information on the dyes used during their production and their link with those used in the silk industry in previous centuries, and to ascertain their state of conservation. Moreover, the images in LM, SEM and CM are contributing to the development of a 3D virtual loom that will favor more accessible and inclusive museography in museums specialized in the silk sector. Both the study of dyes and silk fibers and their virtual reproduction through artificial intelligence programs applied to the study of cultural heritage, by specialists from the Robotics Institute of the Universitat de València, has been developed in the framework of the SILKNOW project (https://silknow.eu/).

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Author Biographies

María Luisa Vázquez de Ágredos Pascual, ARSMAYA research group, Department of Art History, Universitat de València, Spain

She holds a doctorate in geography and history from the Univesitat de València, and a second doctorate in art history from the Universitat Politècnica de València (Spain). She has taught in the Department of Art History, Universitat de València, since 2009. Belongs to the ARSMAYA research group, Universitat de València. Her research focuses on archaeometric and cultural studies of drugs, colors and aromatics in antiquity, from ancient cultures from America and Europe. She is PI of the Roma Hispana project. Artificial Intelligence and New Technologies applied to the study, musealization and dissemination of Spanish cultural heritage in Rome: la spezieria de Santa Maria della Scala (AICO 2020/083; Generalitat Valenciana). She is also PI of the project: Optimization of a Multiband Spectral System of Artistic Diagnosis focused to the implementation of innovative, sustainable and accessible Museum Itineraries: towards a Cultural Tourism in the key of Science, Inclusion and Well-Being applied to great Art Galleries (EU FEDER- Gen-eralitat Valenciana (ID-FEDER / 2021/076). She has been a member of the SILKNOW project (No 769504; European Union's Horizon 2020). She is author of numerous articles in specialized journals, such as Archaeometry, Journal of Archaeological Science, Journal of Cultural Heritage, or Analytical Chemistry, among others, book chap-ters and books in prestigious publishing, such as Universidad Nacional Autónoma de México, the British Archeological Reports, Cambridge University Press, New Mexico University Press, among others

Rosa Herráez-Hernandez, MINTOTA research group, Departament de Química Analítica, Facultat de Química, Universitat de València, Spain

Rosa Herráez-Hernández (Researcher ID: K-5645-2014; https://orcid.org/0000-0002-5106-0826) got a BSc degree in Chemistry in 1989, and the Ph. D. degree in 1992, both in the University of València. From 1992 she has been teaching analytical chemistry in the faculties of Chemistry, Pharmacy, Physics and Biology, and in the Technical School of Engineering. Since 2012 she is a full professor at the Department of Analytical Chemistry of the Universitat de València. Her research work has been carried out in the research group MINTOTA mainly in projects related to the analysis of drugs and environmental pollutants by chromatographic and spectroscopic techniques. She is co-author of more than 100 scientific publications, such as articles in specialized international magazines and different book chapters, and she has participated in numerous scientific congresses. She is also a member of panel experts of different quality agencies and specialized journals.

Pilar Campíns-Falcó, MINTOTA research group, Departament de Química Analítica, Facultat de Química, Universitat de València, Spain

Pilar Campíns Falcó (orcid.org/0000-0002-0980-8298) got the BSc degree in Chemistry in the Faculty of Chemistry of the Universitat de València (1976-1981), and the Ph. D. (1985) with Doctorate Award. From January 2002, she is Professor of Analytic Chemistry. She has supervised more than fifty research projects sponsored by public or private organizations related to: several industrial processes and environmental studies as regards pollutants, clinic studies in drug design and tumor markers (more than 250 published papers and 20 supervised Ph D). She has also experience on university management, she was the Vicerector of research and scientific policy of the University of Valencia since April 2014 to 2018. She founded in 1986 the miniaturization and total analysis methods (MINTOTA) research group. MINTOTA (http://mintota.com/) works in collaboration with other research groups and sectors, it has expertise in knowledge-innovation process (five patents). MINTOTA combines knowledge from chemical reactions, (nano)materials, transduction, calibration, accuracy, quality, sustainability, metrology, multiresidue analysis, solid phase (micro)extraction, chromatography, and in-situ analysis in several fields.

Lucía Rojo Iranzo , Technician of the Laboratory of Analysis and Diagnosis of Work of Art, Department of Art History, Universitat de València, Spain

Technician of the Laboratory of Analysis and Diagnosis of Work of Art, Universitat de València ; Department of Art History, Universitat de València, Avenida Blasco Ibáñez 28, 46010 València, Spain.

Ester Alba Pagán , VALuART research group, Department of Art History, Universitat de València, Spain

She is a tenured professor in the Department of Art History at the University of Valencia. She has a degree in Geography and History, specializing in Art History, and a PhD in Art History from the Universitat de València. She is an extraordinary award for a Bachelor's and Doctorate from the University of Valencia and an Ac-ademic Recognition Award from the Generalitat Valenciana. She has recognized 4 six-year research and 4 five-year teaching. Her research activity focuses on the study and analysis of museology and museography and art criticism, with special attention to contemporary art and cultural heritage linked to the exchange and dissemination of ideas and knowledge, from the perspective of visual studies and the gender perspective. She has been the PI of the SILKNOW project: Silk Heritage in the Knowledge Society: from punched cards to big data, deep learning and visual / tangible simulations (Research and innovation program under grant agreement No 769504; European Union’s Horizon 2020)

References

AHMED, H. E., DARWISH, S. S. (2012). “Effect of museum conditions on historical dyed silk fabric with madder dye”, Journal of Polymers and the Environment, 20: 596-606. https://doi.org/10.1007/s10924-012-0421-x.

AL-SHARAIRI, N., SANDU, I. C. A., VASILACHE, V., SANDU, I. (2020). “Recognition of natural silk fibers, dyes and metal threads of historical Romanian textile fragments using the multi-analytical techniques approach”. Textile Research Journal, 90 (15-16): 1671-1688. https://doi.org/10.1177/0040517519898827.

BADILLO-SANCHEZ, D., CHELAZZI, D., GIORGI, R., CINCINELLI, A., BAGLIONI, P. (2019). “Understanding the structural degradation of South American historical silk: a focal plane array (FPA) FTIR and multivariate analysis”. Scientific Reports, 9: 17239. https://doi.org/10.1038/s41598-019-53763-5.

BARBACHE, S., LAMHASNI, T., EL BAKKALI, A., LYAZIDI, S. A., HADDAD, M., BEN-NCER, A., HNACH, M. (2018). “Optical analyses of wool dyeing materials in ancient Moroccan carpets “Zarbia(s)”: combination of UV-Vis diffuse reflectance, 3D-fluorescence and raman spectroscopies”. Dyes and Pigments, 153: 256-265. https://doi.org/10.1016/j.dyepig.2018.02.033.

BOULET-AUDET, M., VOLLRATH, F., HOLLAND, C. (2015). “Identification and classification of silks using infrared spectroscopy”. Journal of Experimental Biology, 218: 3138-3149. https://doi.org/10.1242/jeb.128306.

DE FERRI, L., TRIPODI, R., MARTIGNON, A., FERRARI, E. S., LAGRUTTA-DÍAZ, A. C., VALLOT-TO, D., POJANA G. (2018). “Non-invasive study of natural dyes on historical textiles from the collection of Michelangelo Guggenheim”. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 204: 548-567. https://doi.org/10.1016/j.saa.2018.06.026.

DING, L., GONG, T., WANG, B., YANG, Q., LIU, W., PEMO, R., METOK, T. (2021). “Non-invasive study of natural dyes in textiles of the Qing Dynasty using fiber optic reflectance spectroscopy”. Journal of Cul-tural Heritage, 47: 69-78. https://doi.org/10.1016/j.culher.2020.10.013.

FONSECA, B., PATTERSON, C. S., GANIO, M., MACLENNAN, D., TRENTELMAN, K. (2019). “Seeing red: towards an improved protocol for the identification of madder and cochineal-based pigments by fiber optics reflectance spectroscopy (FORS)”. Heritage Science, 7: 92. https://doi.org/10.1186/s40494-019-0335-1.

GAITAN, M., ALBA, E. LEÓN, A., PÉREZ, M. SEVILLA, J., PORTALES, C. (2019). “Towards the Preservation and Dissemination of Historical Silk Weaving Techniques in the Digital Era”. Heritage 2 (3), 1892-1911; https://doi.org/10.3390/heritage2030115

GULMINI, M., IDONE, A., DIANA, E., GASTALDI, D., VAUDAN, D., ACETO, M. (2013). “Identification of dyestuffs in historical textiles: strong and weak points of a non-invasive approach”. Dyes and Pigments, 98: 136-145. https://doi.org/10.1016/j.dyepig.2013.02.010.

HACKE , M. (2008). Weighted silk: history, analysis and conservation. Studies in Conservation, 53 (2): 3-15, https://doi.org/10.1179/sic.2008.53.Supplement-2.3

HAN, J., WANROOIJ, J., VAN BOMMEL, M., QUYE, A. (2017). “Characterization of chemical components for identifying historical Chinese textile dyes by ultra high performance liquid chromatography-photodiode array electrospray ionisation mass spectrometry”. Journal of Chromatography A, 1479: 87-96. http://dx.doi.org/10.1016/j.chroma.2016.11.044.

KAPLAN, D., WADE ADAMS, W., FARMER, B. and VINEY C. (1994). "Silk: Biology, structure, properties and genetics", en D. Kaplan, W. W. Adams, B. Farmer y C. Viney (eds.), Silk Polymers: Materials Science and Biotechnology, Washington D.C., ACs Publications, 2–16.

KIM, S., SEONG, H., HER, Y., CHUN, J. (2019). “A study of the development and improvement of fashion products using a FDM type 3D printer”. Fash Text 6, 9. https://doi.org/10.1186/s40691-018-0162-0

KOPERSKA, M., ŁOJEWSKI, T., ŁOJEWSKA, J. (2011). “Vibrational spectroscopy to study degradation of natural dyes. Assessment of oxygen-free cassette for safe exposition of artefacts”. Analytical and Bioanalytical Chemistry, 399: 3271-3283.

KRAMELL, A. E., GARCÍA-ALTARES, M., PÖTSCH, M., KLUGE, R., ROTHER, A., HAUSE, G., HERTWECK, C., CSUK, R. (2019). “Mapping natural dyes in archaeological textiles by imaging mass spec-trometry”. Scientific Reports, 9: 2331. https://doi.org/10.1038/s41598-019-38706-4.

MA, M., HUSSAIN, M., DONG, S., ZHOU, W. (2016). “Characterization of the pigment in naturally yellow-colored domestic silk”. Dyes and Pigments, 124: 6-11. http://dx.doi.org/10.1016/j.dyepig.2015.08.003.

MIKOLAYCHUK, E., PINYAGNA, N. (1997). “Silk as a textile material, reasons of destruction”, en stf Jubilee Conference: Silk. Different Aspects, Estocolmo, Urram, s/f.

MILLER, J.E., REAGAN, B.M. (1989). "Degradation in weighted and unweighted historic silks". Journal of the American Institute for Conservation 28 (2): 97–115.

MILLINGTON, K. R. (2012). “Diffuse reflectance of fibrous proteins”. Amino Acids, 43: 1277-1285. https://doi.org /10.1007/s00726-011-1201-y.

MOINI, M., ROLLMAN, C. M. (2017). “Buyid silk and the tale of Bibi Shahrbanu: identification of biomarkers of artificial aging (forgery) of silk”. Analytical Chemistry, 89: 10158-10161. https://doi.org/10.1021/acs.analchem.7b02854.

PETROVICIU, I., TEODORESCU, I., ALBU, F., VIRGOLICI, M., NAGODA, E., MEDVEDOVICI A. (2019). “Dyes and biological sources in nineteenth to twentieth century ethnographic textiles from Transylvania, Romania”. Heritage Science, 7: 15. https://doi.org/10.1186/s40494-019-0255-0.

POTTIER, F., MICHELIN, A., KWIMANG, S., ANDRAUD, C., GOUBARD, F., LAVÉDRINE, B. (2019). “Macroscopic reflectance spectral imaging to reveal multiple and complementary types of information for the non-invasive study of an entire polychromatic manuscript”. Journal of Cultural Heritage, 35: 1-15. https://doi.org/10.1016/j.culher.2018.06.001.

SHAHID, M., WERTZ, J., DEGANO, I., ACETO, M., KHAN, M. I., QUYE, A. (2019). “Analytical methods for determination of anthraquinone dyes in historical textiles: a review”. Analytica Chimica Acta, 1083: 58-87. https://doi.org/10.1016/j.aca.2019.07.009

TAMBURINI, D., DYER, J., DAVIT, P., ACETO, M., TURINA, V., BORLA, M., VENDENBEUSCH, M., GULMINE, M. (2019a). “Compositional and micromorphological characterization of red colorants in ar-chaeological textiles from pharaonic Egypt”. Molecules, 24: 3761. https://www.mdpi.com/1420-3049/24/20/3761.

TAMBURINI, D., CARTWRIGHT, C. R., PULLAN, M., VICKERS, H. (2019b). “An investigation of the dye palette in Chinese silk embroidery from Dunhuang (Tang dynasty)”. Archaeological and Anthropological Sciences, 11: 1221-1239. https://doi.org/10.1007/s12520-017-0592-4.

TAMBURINI, D., DYER, J. (2019). “Fiber optic reflectance spectroscopy and multispectral imaging for the non-invasive invstigation of Asian colourants in Chinese textiles from Dunhuang (7th-10th century AD)”. Dyes and Pigments, 162: 494-511. https://doi.org/10.1016/j.dyepig.2018.10.054.

TAMBURINI, D. (2019). “Investigating Asian colourants in Chinese textiles from Dunhuang (7th-10th Centu-ry AD) by high performance liquid chromatography tandem mass spectrometry – Towards the creation of a mass spectra database. Dyes and Pigments, 163: 454-474. https://doi.org/10.1016/j.dyepig.2018.12.025.

VERHECKEN, A., STORME, P., SCHALM, O. (2014). “UV-Vis reflectance spectrometry study of the dyed silks in a relic shrine found in Antwerp, Belgium”. e-Preservation Science, 11: 99-104.

Published
2022-06-16
How to Cite
Vázquez de Ágredos Pascual, M. L., Herráez-Hernandez, R., Campíns-Falcó, P., Rojo Iranzo , L., & Alba Pagán , E. (2022). Color study of historic silks . Ge-Conservacion, 21(1), 246-256. https://doi.org/10.37558/gec.v21i1.1133